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Rationalizing Unusual Kinetics in C-H Activations

Typically, traditional methods of initial rate measurements require many experiments run under artificially high concentrations of reaction components, potentially diminishing the practicality and utility of kinetic analysis. In contrast, Reaction Progress Kinetic Analysis (RPKA) extracts a maximum amount of kinetic information from a minimal number of experiments run under synthetically relevant conditions. Simple graphical manipulations of reaction progressions probe catalyst stability and reveal kinetic driving forces of reaction components by visual inspection. The RPKA methodology is used in the context of palladium-catalyzed C-H olefinations of arylacetic acids to explain anomalous rate behavior including the inhibitory action of several off-cycle catalytic species. This webinar is for chemists, engineers and researchers interested in reaction kinetics, as well as anyone who finds it difficult or time consuming to determine the kinetics and reaction behavior of chemistry.

Type of Event: On-Demand Webinars
By appointment: Yes
Language: English

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