My watch list


Electrochemical extraction of energy from seawater

Power generator autonomously switches between two functional modes

© Wiley-VCH

15-May-2019: Underwater vehicles, diving robots, and detectors require their own energy supply to operate for long periods independent of ships. A new, inexpensive system for the direct electrochemical extraction of energy from seawater offers the advantage of also being able to handle short spikes in power demand, while maintaining longer term steady power. To do so, the system can autonomously switch between two modes of operation, as researchers report in the journal Angewandte Chemie.

Charting submarine landforms, currents, and temperatures, and inspecting and repairing pipelines and deep-sea cables are just a few examples of tasks carried out autonomously by underwater devices in the depths of the ocean. Under these extreme conditions, the challenge for power generators is to produce both a high energy density (long run time with basic power use) and high power density (short-term high current flow) for activities such as rapid movement or action of a gripper.

Liang Tang, Hu Jiang, and Ming Hu and their team from the East China Normal University in Shanghai, Shanghai University, and the Chinese Research Academy of Environmental Sciences in Beijing, China, have taken inspiration from marine organisms that can switch their cell respiration between aerobic and anaerobic modes by using different materials as electron acceptors. The researchers have designed a new power generator that works by the same principles.

The key to the discovery is a cathode made of Prussian blue, an open framework structure with cyanide ions as “struts” and iron ions as “nodes”, which can easily accept and release electrons. When combined with a metal anode, this structure can be used to generate electricity from seawater.

If the power demand is small, the electrons flowing into the cathode are transferred directly to dissolved oxygen. Because dissolved oxygen in seawater is inexhaustible, power at low current can theoretically be provided for an unlimited time. However, the concentration of dissolved oxygen is low. When the power demand, and thus current, are sharply increased, there is not enough oxygen at the cathode to immediately take up all of the incoming electrons. The Prussian blue must therefore store these electrons by reducing the oxidation state of the iron atoms from +3 to +2. To maintain a charge balance, positively charged sodium ions lodge within the framework. Because these are present in high concentration in seawater, many sodium ions—and therefore many electrons—can be absorbed in a short time. When the current demand slows down, electrons are transferred to oxygen once again, oxygen regenerates the framework, Fe2+ is oxidized to Fe3+, and the sodium ions depart.

This new system is very stable in corrosive seawater and can withstand numerous mode switches. It ran continuously for four days in its high-energy mode without losing power. The high-power mode was able to supply 39 light-emitting diodes and a propeller.

Original publication:
Ming Hu et al.; "An Auto‐Switchable Dual‐Mode Seawater Energy Extraction System Enabled by Metal–Organic Frameworks"; Angewandte Chemie International Edition; 2019

Facts, background information, dossiers

More about Angewandte Chemie

  • News

    Staining Cycles with Black Holes

    In the treatment of tumors, microenvironment plays an important role. It often contains immune cells that are so changed that they promote tumor growth. In the journal Angewandte Chemie, scientists have introduced a method by which cell samples from tumors and their surroundings can rapidly ... more

    Amplification and imaging of microRNA as a biomarker to detect tumor development

    A good indicator of dysregulation in live cells is a change in their RNA expression. MicroRNA (miRNA), a special type of RNA, is considered a biomarker for carcinogenic cells. A team of scientists from China has found a way to amplify miRNA in live tumor cells for bioimaging. As they report ... more

    One Drug, Three Action Modes

    Clinicians combat the drug resistances of some cancer types by using a combination of different drugs. To make this approach more effective, chemists have designed a chemical conjugate that can simultaneously attack several cellular targets using different modes of action. Such a single-dru ... more

q&more – the networking platform for quality excellence in lab and process

The q&more concept is to increase the visibility of recent research and innovative solutions, and support the exchange of knowledge. In the broad spectrum of subjects covered, the focus is on achieving maximum quality in highly innovative sectors. As a modern knowledge platform, q&more offers market participants one-of-a-kind networking opportunities. Cutting-edge research is presented by authors of international repute. Attractively presented in a high-quality context, and published in German and English, the original articles introduce new concepts and highlight unconventional solution strategies.

> more about q&more

q&more is supported by:


Your browser is not current. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE